Plastics - Determination of melting behaviour (melting temperature or melting range) of semi-crystalline polymers by capillary tube and polarizing-microscope methods (First revision) (ISO 3146:2000, COR. 1:2002, IDT)
thus International Standards specifies two methods for evaluating the melting behavior of semi-crystalline polymers. Melting temperatures determined by the different methods usually differ by several kelvins for the reasons explained in the introduction.
Method A : Capillary tube
This method is based on the changes in shape of the polymer. it is applicable to all semi-crystalline polymers and their compounds.
NOTE 1 Method A may also be useful for the evaluation of the softening of non-crystalline solids.
Method B: Polarizing microscope
This method is based on changes in the optical properties of the polymer. It is applicable to polymers containing a
birefringent crystalline phase. It may not be suitable for plastics compounds containing pigments and/or other additives
which could interfere with the birefringence of the polymeric crystalline zone.
NOTE 2 Another method applicable to semi-crystalline polymers is described in ISO 11357-3:1999, Plastics — Differential scanning
calorimetry (DSC) — Part 3: Determination of temperature and enthalpy of melting and crystallization.
